Plastic containers for storage of goods under pressure

ABSTRACT

A form-retaining container made of synthetic plastic material and apparatus for its manufacture in which a plastic material is fed in liquid state onto a male member to provide a layer on the male member constituting a blank for the container. The layer is cooled to prevent crystallization of the material. The thus cooled blank is placed into a mold cavity having an interior configuration corresponding to the desired outer shape of the container to be produced. The layer is inflated into conformity with the mold cavity. The configuration of the mold cavity is such that the blank undergoes biaxial stretching in a middle region of the container by at least 1.5 times while the mouth and part of the bottom of the container will be formed by biaxially stretching the blank less than 1.5 times. The inflated blank is then heated until curing is completed and then the blank is removed from the mold.

CROSS-RELATED APPLICATION

This application is a division of Ser. No. 22,320 filed Mar. 20, 1979now issued as U.S. Pat. No. 4,264,558 which in turn is a continuation ofSer. No. 831,785 filed Sept. 9, 1977 (now abandoned) which in turn is acontinuation of Ser. No. 614,430 filed Sept. 18, 1975 (now abandoned).

FIELD OF THE INVENTION

The present invention relates to thermostable plastic containersintended for storage over a certain period of time of goods underpressure, such as preserves, milk and milk-like products and the likeand wherein containers can be reused a number of times.

PRIOR ART

For a long time, there has been a desire to achieve plastic containerssuitable for the above-mentioned uses. Special containers for storage ofgoods under pressure are also known. As a rule, such known containershave a cylindrical form, which in turn involves that the bottom portionbecomes particularly subjected to stresses, due to the internal excesspressure. In order to fulfill the requirements for strength at thebottom of the containers, a great number of bottom configurations havebeen developed. It is also known to work with reinforcements insertedinto the region in question. Hitherto known solutions for achievingplastic containers for storage of goods under pressure show poorproperties as regards the capability of retaining shape and strength, asthey soften when heated. If such a container is used for storage of e.g.beer or beverages, the temperature sensitivity is, of course, a seriousdrawback, since heating of a liquid containing carbonic acid causes anincrease of the pressure in the container, at the same time as thestrength of the plastic walls of the container decreases.

It is sometimes required that containers for storage of preservessatisfy the requirement of being filled with hot goods. Furthermore, thecontainers must withstand the sterilizing required for the method ofstorage. For storage of milk or milk-like products, there is arequirement that the containers withstand the temperature at whichpasteurization takes place.

With certain applications, the containers need to be filled with goodsthat have temperatures exceeding 100° C. For example, in medicalapplications autoclaving is used. In these applications, there also aresevere requirements on the capability of the containers of withstandinghigh temperatures.

For containers of the type that are reused, it is required that theywithstand the cleaning necessary for the repeated use, and thetemperature and cleaning agents which are applied.

Containers made of thermoplastic material which are intended for theabove-mentioned uses have hitherto been available only to a limitedextent. In order to achieve the properties required to some extent, inprinciple, it has been attempted to obtain compositions of plasticmaterial that are suitable for the special application, and attemptshave also been made to give the containers such a shape that thestrength of the material has been utilized as much as possible. The mainproblem is that the thermoplastics soften as the temperature increases,which has a detrimental effect on the strength of the containers. Onemeans for achieving greater strength of the plastics used has been tostretch the material within the thermoelastic temperature range and thencool it, which results in a so-called biaxial orientation. There is alsoa risk that the container will change its shape at an increasedtemperature, due to the fact that the stresses that are built into thematerial in conjunction with the forming of the container are releasedat the higher temperature.

The properties of plastic containers which primarily have caused allattempts to find solutions are the low weight and the possibility ofproducing containers with better capability of withstanding impacts andshocks than that of conventional glass container.

Plastic material suitable for the above-mentioned purposes is moreexpensive per volume unit than glass. The has had a retarding effect onthe possibilities of changing from containers made of glass tocontainers made of plastic. It has not been feasible to compensate theinferior temperature properties of the plastic container with anincreased wall thickness of the container. Instead, for economicreasons, it has been necessary to have walls as thin as possible, andalso to accept the drawbacks thereby involved.

Furthermore, no plastic material is known which is commercially suitablefor use in containers intended for reuse, for the previously mentionedpurposes, with the requirements such use involves.

SUMMARY OF THE INVENTION

According to the present invention, thermoplastic material in the formof a hollow member is treated so that the above-mentioned drawbacks ofthe thermoplastic material are eliminated and the above-mentionedapplications for the plastic material can be permitted in general.

The invention discloses the possibility of shaping thermoplasticmaterial into a hollow member so that it retains its shape permanently,and also retains its strength properties even if the hollow member isheated to very high temperatures. Practical tests have shown, forexample, that a container, the wall of which consists of a thermoplasticmaterial treated according to the invention, can be heated to 240° C.without the container changing shape. Furthermore, the material stillhas good strength at this temperature. Moreover, the material retainsits good strength properties at low temperatures. The material canthereby be used for containers intended for storage of products whichare kept in a frozen condition. In other tests, containers consisting ofwall material treated according to the invention have been sterilized at121° C. for an hour, and there have not been any changes in the shape ofthe container or any of its other properties. Furthermore, hot liquid ata temperature of 130° C. has been filled into containers made accordingto the invention, and this has not caused any change in shape orstrength.

Material suitable for treatment according to the invention iscrystallizable thermoplastic polymer plastic. In the following, theexpression "crystallizable polymer plastics" refers to those synthetic,linear, organic polymer plastics that can be obtained in an essentiallyamorphous condition, and that can be transformed into a crystalline formthrough heating to temperatures above the melting point of the material,whereupon it is cooled slowly to room temperature. The substantiallyamorphous material is obtained by a rapid cooling of the melted polymerplastic. Crystallizable polymer plastics suitable for use in themanufacture of hollow members according to the invention are polyethleneterephthalate, polyhexamethylene adipamide, polycaprolactam,polyhexamethylene sebacamide, polyethylene 2,6 and 1,5 naphthalate,polytetramethylene-1,2-dioxybenzoate, and copolymers ofethyelen-terephthalate and ethylene isophthalate, and other similarpolymer pastics. The invention is described with reference to a polymerplastic designated Akzo polyester Arnite 210, but the invention isapplicable generally to crystallizable polymer plastics, of whichexamples are given above. The temperatures indicated in the followingprimarily refer to Akzo polyester Arnite 210.

The invention is based upon the fact that the above-mentioned materialscan be treated so that they are in any one of five property ranges eachof which is defined hereafter.

Property range 1: Crystalline

In this property range the material is strong, hard, and has formstability, but is somewhat brittle. The uncolored material is milkywhite and opaque. Its properties are changed only to a slight degreewith temperature, and measurements have shown that in the vicinity ofthe melting temperature of 255° C. the material substantially retainsits above-mentioned properties. The material is transformed to theproperty range if, from a melted condition, it is allowed to coolwithout forced cooling. The material is then crystallized, and the clearor transparent appearance in the melted condition is changed to theabove-mentioned milky white appearance. The material can also betransformed to this property range from property range 2, which isdefined below. The procedure is then that the material, when it is inproperty range 2, is heated to a temperature exceeding approximately100° C. and is held at this temperature for a certain time, and thematerial is then crystallized. At 140° C. the crystallization takesplace very rapidly.

Property range 2: Amorphous

In this property range the material is somewhat less strong and hard andhas somewhat less form stability than in property range 1. Instead, itis somewhat tougher. Further, it is clear and transparent. When heated,the material softens at approximately 70° C. and assumes a rubber-likecharacter. It can be held at 100° C. for a long time without thematerial being changed, but if the temperature is raised further, thematerial begins to crystallize. Cf. property range 1, above. Thematerial is transformed to this property range if it is rapidly cooledfrom the melted condition to a temperature of 100° C. or lower, thematerial then not having time to crystallize. Further, the material canbe transformed into this property range from property range 3, which isdefined below. This takes place if the material, when it is in propertyrange 3, is heated to a temperature of 70° C. or higher, whichtemperature, however, must not exceed approximately 100° C.

Property range 3: Amorphous, elastic and stretched

In this property range the material has the corresponding properties aswhen it is in property range 2, with the exception of its behavior atthe heating to the temperature range between 70° and 100° C. Thebehavior of the material then will be described in the following. Thematerial is transformed into this property range from property range 2by heating the material when it is in property range 2 to a temperatureof between 70° and 140° C., and while it is at this temperature it isstretched to a maximum of 1.3-1.5 times its original length. In thestretched condition, the material is then cooled to a temperature below70° C. Internal stresses are then built into the material, which has theresult that the material, when heated again to a temperature of between70° and 140° C., returns to the length it had before the above-mentionedstretching took place.

From the description given above, it will also be noted that if thematerial, when it is in property range 3, is heated to 140° C. or more,for a sufficiently long time, the material will first be transformedinto property range 2, as soon as the temperature passes 70° C., andthereafter into property range 1, when the crystallization commences, ata further increased temperature. If the heating takes place with thestretching of the material maintained, the crystallization will takeplace also in this case, and the material will then also be transformedinto property range 1, but it will then retain its greater length.

Property range 4

In this property range the material is entirely clear and transparent.It is very tough, and is moreover relatively strong and has relativelygood form stability. The material retains its clearness even if it isheated to very high temperatures, even temperatures that are in thevicinity of the melting point of the material which, for the material inquestion, is 255° C. When the material is heated to temperatures above70° C. a certain minor contraction of the material takes place, as theelastic stretching is released, but the plastic one remains.

The material is transformed into this property range by a procedurecorresponding to the one for transforming the material into propertyrange 3. From the beginning, it is thus to be in property range 2, andis heated to a temperature of between 70° and 140° C., after which it isstretched to more than 1.5 times its original length while it is stillat the temperature to which it has been heated. Thereafter the materialis cooled to a temperature of below 70° C., at the same time as it isstill kept stretched. Certain internal stresses are thereby built intothe material so that when the material is heated again to a temperatureexceeding 70° C., it contracts somewhat. However, this contraction isless than the one corresponding to the previous stretching of thematerial.

Property range 5

In this property range, the material has substantially the sameproperties as when it is in property range 4. Thus, it is entirely clearand transparent, very tough, relatively strong, and has relatively goodform stability. Further to this, contrary to the case of when it is inproperty range 4, it retains its shape when heated, even if it is heatedto a very high temperature, i.e. above 140° C.

The material is transformed into property range 5 from property range 4.This takes place by the material, when it is in property range 4, beingheated for a sufficiently long time--in the order of seconds tominutes--to a temperature above 140° C., at the same time as thematerial is forced to retain its shape. The internal stresses which werebuilt into the material at its orientation and which as regards thematerial in property range 4 result in a certain contraction of thematerial when it is heated to temperatures above 70° C. are thenreleased.

As stated above, in order to transform the material into property range3 or 4, certain stretching of the material must take place. At thisstretching, the molecules of the material are oriented. It should bequite obvious that this stretching and orientation can be effected inmore than one direction, whereby the orientation will be of a biaxialnature. Through the biaxial orientation, it is achieved that thestrength of the material will be more independent of the direction inwhich the stressing takes place.

It is, of course, of great interest to be able to produce containersmade of crystallizable polymer plastic, where the material of thecontainers is in property range 1 or in property range 5. The intentionis then primarily that the bottom and mouth parts are in property range1, while the material in the other parts of the container are inproperty range 5. If the procedure according to the invention is appliedto a device for producing a bottle or crystallizable polymer plastic, abottle is thus obtained in which, for example, the mouth part, the upperparts of the neck, and parts of the bottom section contain materialwhich is in property range 1, while the other parts of the bottle are inproperty range 5. A bottle made in this way thus has a mouth with verygood form stability, on which a cap can be fastened, a bottom with goodform stability, very capable of withstanding internal overpressurewithout changing its shape, and at the same time the other parts of thebottle have great resistance to impacts and shocks. Further, a bottleformed in this way has a body which is substantially clear andtransparent.

According to the invention, a container, for instance a bottle, is madein three steps. In the first step, a blank is formed in such a way thatthe material of the blank is in property range 2, in the second step theblank is widened to form a bottle, in which the cylindrical part of thebottle and sections of the neck and bottom are in property range 4,while the remaining parts of the bottle are in property range 2 or 3,and in the last step the parts of the bottle which previously were inproperty range 4 are transformed into property range 5, while the otherparts of the bottle are transformed into property range 1. In this way abottle is made which is built up in a way corresponding to the buildingup in principle which is described in the foregoing paragraph.

In practice, the blank can consist, for example, of an injection moldedmember or of an extruded tube which, upon manufacture, is cooled sorapidly that the material is in property range 2. In the second step theblank is transferred to a blow molding station, where the blank isexpanded to the dimensions which the finished bottle is to have. Theexpansion takes place at a temperature of between 70° C. and 140° C. or,more generally speaking, at a temperature that is above theglass-transition temperature but below the crystallization temperature.Further, the blank has such dimensions that the cylindrical part of thebottle and parts of the neck and bottom regions will have theirdiameters increased at least 1.5 times. Thereafter, the bottle caneither be transferred to a new station or remain in the station where itis. With an internal over-pressure in the bottle so that it is pressedagainst the walls of the mold used, the temperature of the material inthe bottle is raised to above 140° C. or, more generally expressed, toabove the temperature of maximal crystallization for such a long timethat the stresses built into the material are released. The timerequired for this varies from seconds to minutes, depending on thetemperature used and the material used. The parts of the material in thebottle that have been expanded at least 1.5 times have now beentransformed into property range 5. The other parts of the bottle are inproperty range 1. In the final stage of the process, a temperaturestabilization thus takes place. This need not be carried out inconnection with the blow molding, but the molded bottles can very wellbe cooled down to room temperature, and on some later occasion besubjected to the temperature stabilization.

BRIEF DESCRIPTION OF THE DRAWINGS

The invention will be described in more detail with reference to theappended drawings, wherein:

FIGS. 1 and 1A show respectively a blank and a finished bottle moldedfrom the blank; and

FIG. 2 diagrammatically shows a device for producing a bottle accordingto the invention.

DETAILED DESCRIPTION

FIG. 1 shows a blank 10, which is to be molded into a finished bottle11. In the blank, a portion 12 in the bottom part is indicated, whichcan be in a crystallized form, i.e. in property range 1. In the finishedbottle, three portions are indicated, namely portion D₁ comprising themouth part and part of the neck, portion D₂ comprising the remainingpart of the neck, the cylindrical part of the bottle and part of thebottom and, finally, portion D₃ comprising substantially the centralportion of the bottom.

FIG. 2 shows apparatus for producing the bottle comprising a wheel 13,which rotates in steps, on which four male parts 18, 19, 20, 21 arearranged. Each male part is provided with a number of tempering channels15, through which tempering medium can flow. When a male part is in theposition of the male part 18, the male part coacts with a blank-formingpart 16 and an injection device 17 with a nozzle 14. When a male part isin the position of the male part 20, the male part coaxts with a splitmold 26, for forming the bottle, the inner surface of the moldcorresponding to the form of the finished bottle. In the position of themale part 21, the male part coacts with a split outer mold 22 for thetemperature stabilization or control of the bottle. The outer mold 22for the temperature control is provided with channels or ducts 25 fortempering fluid. The valves that regulate the supply of the temperingfluid that flows through the channels of the male parts and through thechannels of the outer molds, as well as other regulating and controldevices, are not shown in the figure and they are conventional. Thefigure also shows a molded but not temperature-stabilized bottle 23 anda molded and temperature-stabilized bottle 24. The outer devices whichcoact with the male parts--blank forming part with injection device, theouter mold for forming the bottles and the outer mold for thethermostabilization--are shown in the position they have when therotating wheel is to be moved one step.

The device operates in the following manner. Starting material in theform of crystallizable thermoplastic polymer plastic is fed to theinjection device 17 in a solid or liquid form. Suitable and conventionaldevices open the nozzle 14 for an appropriate time interval, so that anappropriate quantity of plastic material is applied to the male part 18.This entire procedure takes place according to known technology.According to the invention, the plastic material, when it reaches themale part, is cooled so rapidly that the material does not crystallize,but is transformed into property range 2, previously described in thisspecification. If, in the following, it is assumed that the device isfed with the previously mentioned polymer plastic Akzo polyester 210,the plastic is cooled to a temperature of below 100° C. The blank isthereafter transferred to the next step of the rotating wheel, where itmay possibly be tempered. Both in this position and in the foregoingone, the tempering of the blank takes place with the aid of thetempering channels 15. The male parts are moreover made of material withgood heat conductivity.

When the temperature of the blank has reached the predetermined value,the wheel is rotated another step. The material of the blank then has atemperature of between 70° and 140° C. The male part 20, with the blankpositioned on it, is now enclosed by the two halves of the outer mold 26for the forming of the bottle, whereupon the blank is blown up againstthe inner walls of the mold. Depending on the stretching of thematerial, the plastic in the bottle will thereafter be in one of theproperty ranges 2, 3 or 4. At the contact against the outer mold, thematerial is cooled to a temperature of below 70° C., i.e. thetemperature above which the orientation stresses in the material arereleased.

The molded but not temperature-stabilized bottle 23 is now transferredto the next station after the two halves of the outer mold have beenopened and the rotating wheel rotated one step. The bottle is enclosedby the two halves of the mold of thermostabilization which are kept atan appropriate temperature by the tempering medium flowing through thechannels for tempering fluid. The inner parts of the mold are made of amaterial that has good heat conductivity. The plastic material of thebottle is thereby kept at a temperature above 140° C., at the same timeas the bottle is subjected to an internal pressure, pressing the wallsof the bottle against the inner walls of the mold. The parts of thebottle which were previously in property range 4 are thereby transformedinto property range 5. All other material crystallizes, and will thus,after the processing has been completed, be in property range 1. Thetime for which this processing must be carried out so that all of thematerial is transformed into property range 5 or 1 varies betweenseconds to minutes. The time depends upon the temperature used and onthe plastic material used. When the procedure has been completed, theshape of the bottle conforms to the inner surface of the outer mold. Thehalves of the mold move aside, the bottle is blown loose from the malepart, and leaves the molding device. The wheel is rotated another step,and the male part again comes into the position for receiving plasticmaterial to form a new blank 10.

The sizes of the portions or regions D₁ and D₃ are determined by thestretching of the material that takes place in connection with theblowing of the blank into the form of a bottle. In both of theseregions, the material is in property range 1 which requires that thestretching of the material is less than 1.5 times in connection with theblowing. It should thus be obvious that the sizes of the regions can beregulated by appropriate combinations of the shape of the blank and theshape of a finished bottle. It is thus possible to choose these twoshapes in such a way that portions or regions will be partly or entirelyeliminated. The reshaping from the blank into the bottle involves thatthe material is stretched in more than one direction, since, as a rule,the bottle is longer than the blank in the axial direction.

In portion or region D₂ the material is in property range 5, since thematerial, in connection with the reshaping of the blank, has beenstretched at least 1.5 times.

It should be obvious that the blank need not have the substantiallycylindrical form shown in FIG. 1. In order to achieve the specialcombinations of regions containing material within property range 1 andproperty range 5, respectively, which are desired in each individualproduction series, it may be necessary to give the blank a moreirregular shape. If, for instance, it is desired that the finishedbottle should have one or several rings of material which are inproperty range 1 in its cylindrical part, the blank should be made withcorresponding cylindrical bulges, so that the material, when the blankis formed into a bottle, will be stretched to such a small extent--lessthan 1.5 times--that the material will be in property range 3. At thethermostabilization carried out in the final step, this material willcrystallize and will be transformed into property range 1.

The material which is in property range 1 is crystallized and opaque, atthe same time as it has a milky white appearance. This gives the bottlea characteristic appearance. As previously mentioned, bottles madeaccording to the invention can be reused, since they will withstand thecleaning procedures required for their reuse. It has previously alsobeen shown that the size of the milky white portion or region designatedD₁ can be controlled through an adaptation of the diameter of the blankin relation to the corresponding diameters of the finished bottle. Anesthetically attractive size of the milky white region can thus beobtained. At the same time, this milky white region can be allowed toconstitute a readily identified indication that the bottle is intendedfor reuse.

In certain examples of the application it is desired that the bottompart has a flat section of material in property range 1. This makes saidpart of the bottom very rigid, and it will be more or less as though ithad been provided with a reinforcement such as a piece of metal. Thesize of this rigid flat section can be controlled by means ofappropriate combinations of the shape of the blank and the final shapeof the bottle. According to another alternative for achieving thiscondition with a rigid section of the material which is in propertyrange 1 and located in the bottom region of the bottle, the bottom partof the blank is allowed to cool so slowly that the material in thebottom part crystallizes. Cf. the crystallized range 12 shown in FIG. 1.In certain cases there can also be difficulities involved in achievingsufficiently efficient cooling in the vicinity of the nozzle of theinjection device, and this leads to the crystallized region 12 shown inFIG. 1.

The production operation according to the invention also provides thepossibility of providing a container with a wide opening, the mouthsection of the container consisting of crystallized thermoplasticpolymer plastic, i.e. of material which is in property range 1, asdefined above. The other parts of the material in the container are inproperty range 5, possibly with the exception of certain parts of thebottom. In this way, a mouth part with form stability, well adapted tobe closed, is obtained. The temperature stability of the mouth part alsoinsures that the tightness of the closure, in principle, is not affectedby temperature variations.

In the description above, it has been assumed that the temperaturestabilization has been carried out in a special processing station.However, the temperature stabilization can, of course, also be carriedout at the same station at which the reshaping of the blank to form afinished bottle takes place. The outer mold is then provided withchannels for tempering, in the same way as indicated in the foregoing inregard to the outer mold for thermostabilization. In this way, thespecial thermostabilization station can be eliminated. The disadvantageof the alternative embodiment is that the production rate will be lower.

The temperature stabilization can also be carried out in specialtemperature stabilization machines. Already known and already installedmachinery can thereby be used for the production of bottles according tothe invention. The bottles made in such machines will thus contain wallmaterial which is in one of the property ranges 2, 3 or 4, as in thecase of the bottles which have not yet been temperature-stabilized inthe device for the production of bottles which has previously beendescribed in this specification.

The bottles which are produced in existing machinery and which thus havenot been temperature-stabilized, are inserted in separatetemperature-stabilization machines, in which, in the corresponding wayas has been described previously, they are pressed against the walls ofthe molds in the temperature-stabilization machines, by means of anoverpressure, at an appropriate temperature and for the time required.

It will hereby be found that the invention can be applied to existingmachinery, utilizing its maximum production capacity. Thetemperature-stabilization is thereafter carried out in separateequipment, and the capacity of this equipment can then be adapted to thecapacity of the existing machinery.

The description given above of an embodiment of the invention is only tobe regarded as one example of the invention. Trials have shown that ithas been easy to adapt machines of various known types to meet thespecial temperature requirements indicated for the production ofcontainers according to the invention.

As previously mentioned, the above-mentioned temperature data refer tothe polyester Akzo Arnite. For other cyrstallizable thermoplasticpolymer plastics suitable for use in the manufacture of containers ofthe contemplated type, other temperatures may have to be employed. Theseembodiments are also included in the concept of the invention, as avariation of the temperatures in relation to what has been stated abovemerely involves the utilization of the materials within thecorresponding property ranges as those indicated in the description and,accordingly, an application of the means for the production ofcontainers within the contemplation of the invention.

Even after the temperature stabilization of the bottles according to theabove-mentioned description has been carried out, the material in abottle made according to the invention shows a certain tendency towardsa minor contraction when the material in the bottle is heated anew. Inprinciple, this tendency towards a slight shrinking can be eliminatedif, when completing the temperature stabilization of each bottle, theinternal excess pressure in the bottle is allowed to cease, at the sametime as the bottle is allowed to remain in the heated mold for a certainlength of time before it leaves the temperature stabilization station.During this time, the material in the walls of the bottle is still at anelevated temperature, but as the internal excess pressure in the bottlehas ceased, the remaining shrinkage stresses in the material can bereleased, and thereby a slight shrinking of the bottle is released. Whenthis has taken place, the bottle leaves the molding device in the usualway.

What is claimed is:
 1. A form-retaining container made of athermoplastic polymer material selected from the group consisting ofpolyethylene terephthalate, polyhexamethylene adipamide,polycaprolactam, polyhexamethylene sebacamide, polyethylene 2,6 and 1,5naphthalate, polytetramethylene-1,2-dioxybenzoate, and copolymers ofethylene terephthalate and ethylene isophthalate; said containercomprising in succession a mouth, a neck, a main body portion, and abottom including a central portion and a peripheral portion, saidcontainer having a first region inclusive of said mouth and part of saidneck, a second region inclusive of the remainder of said neck, said mainbody portion and said peripheral portion of said bottom, and a thirdregion constituted by said central portion of said bottom, said polymermaterial being selectively heated, cooled and inflated so that saidsecond region is obtained by stretching said material in said secondregion in more than one direction to achieve biaxial stretching andorientation of the material while the material in said first and thirdregions is substantially unoriented, whereafter the material is treatedat a temperature above the crystallization temperature, while beinginternally pressurized to effect thermal crystallization and release ofinternal stresses of said regions such that the first and third regionsare in a thermocrystallized state and provide an opaque appearance whilethe second region has only a small crystallization to provide atransparent appearance, whereby the container is form stable whenreheated to a temperature above the glass transition temperature of thematerial.
 2. A container as claimed in claim 1 wherein said bottom issubstantially flat and consists of crystallized polyester capable ofresisting pressure increase in the container.
 3. A container as claimedin claim 1 wherein said polymer is polyethylene terephthalate.
 4. Acontainer as claimed in claim 1 wherein said polymer is polyethylene 2,6 and 1,5 naphthalate.
 5. A container as claimed in claim 1 wherein saidpolymer is 1,2-polytetramethylene benzoate.
 6. A container as claimed inclaim 1 wherein said polymer is a copolymer of ethylene terephthalateand ethylene isophthalate.
 7. A container as claimed in claim 1 whereinsaid neck is relatively narrow in said first region, said body isrelatively wide in said second region, and said central portion isprotruding in said third region.